In this post let us apply the LCAO method and approximations we studied earlier to a simple conjugated molecule and carry out the calculations for
Tag: Huckel molecular orbital theory
113 – Hückel approximations.
Before we proceed with learning the theory, we must acquaint ourselves with certain terms related to Hückel’s rule. Approximations – The energy of molecular orbitals
112.LCAO approach to HMO theory.
In the last post we got an overview of what matrices are and how they are used. Let us proceed further and see how this
111.Matrix
Before proceeding further, it is imperative that we understand some basic mathematical concepts required to study this theory. We are not going to elaborately study
110.Hückel Molecular theory (HMO).
Hückel’s molecular orbital(HMO) theory. The π- electron system in conjugated planar molecules can be treated independently of the σ framework. Aromaticity is usually described in
83.Covalent Bonding(29) – MOT(4)- LCAO approximation(2).
Configuration means order. The electronic configuration of an element describes how electrons are distributed in various atomic orbitals in the atom. Thus, electronic configuration gives
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