92.CHEMICAL BONDING (39)- Covalent Bonding(38) – Molecular Orbital Theory(13)- Heteronuclear diatomic molecules(2)- HF.

 

From this post onwards, we shall study some examples and learn how bonds are formed between two different atoms.

Hydrogen fluoride (HF)

We begin discussing the simplest of heteronuclear molecule – the HF molecule. In this species, fluorine is more electronegative than hydrogen.As studied in the earlier post, the 2s orbitals are way to low in energy(-40.2eV) to interact with 1s of hydrogen(-13.6eV).

Why are the 2s orbitals so low in energy?
The atomic number of fluorine is 9 i.e there are 9 protons in fluorine atom.Thus, the 1s and 2s electrons , which are near the nucleus, experience a very strong pull(more attraction) from these 9 electrons ,on account of which, they are very tightly bound to the nucleus.Thus, they are further lower in energy than H electrons , which experience pull from a nucleus that has only 1 electron in it.

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As seen in the figure below, the 2s electrons remain non bonding(nb).In classical terms, this is a lone pair of electrons, which DOES NOT take part in bonding. As this orbital does not interact with other orbital, it’s energy remains the same. 

9131.jpg
MO diagram for HF .

 

The 1s of H atom and 2p of F atom are comparable in energy.So, they interact.However, it is only the pz orbital which has the same symmetry around the internuclear axis as the s – orbital.As a result, the 1s of H  overlaps with the porbital of F atom. The px and py orbitals remain unaffected as they are in a different plane.The electrons in these orbitals are non bonding i.e they are lone pairs on F atom. 

914
Overlap between H and F atoms.

 

Thus, there are three lone pairs on F atom and the electrons in BMO are shifted more towards F atom too. This is also seen in the Lewis structure of HF molecule. The δ+ charge indicates that the BMO/electron pair is shifted away from H and δ- indicates a partial negative charge that is developed on F atom as a result of the electron pair shifting towards it.

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We shall continue studying more MO diagrams in the upcoming posts.

Be a perpetual student of life and keep learning….

Good day !

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