94.CHEMICAL BONDING (41)- Co ordinate covalent bond.

This post is dedicated to studying the co-ordinate covalent. This is a bond formed between an electron rich and an electron poor species.

Electron rich species Lewis base  electron donor
Electron deficient/poor species Lewis acid  electron acceptor

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If a rich man and a poor guy become friends, the rich man will lend his extra money to the poor man and they will bond well. Similarly, when an electron rich species(Lewis base) donates its electrons to a electron deficient species(Lewis acid) , a co-ordinate covalent bond is formed between them. In this type of bond, only one atom provides both the shared electrons. The other atom just accepts those electrons. This is different from a covalent bond where electrons are shared by both the atoms.

e.g. – i)Ammonium ion (NH4+) – In this ion, the nitrogen in ammonia molecule has a lone pair of electron.Thus, ammonia is electron rich. The hydrogen ion (H+) is formed when hydrogen looses the 1s electron. Thus, the hydrogen ion is electron deficient.Ammonia lends it’s lone pair to hydrogen ion to form a co ordinate bond between the two. Note that in this bond the electrons shared between two species come from ammonia only.


ii) Ammonia diborane – Just as above, ammonia can end its lone pair to borane molecule, which is electron deficient as follows –


A co ordinate bond is shown by ‘→’ sign.The arrow is drawn from the electron donor to the electron acceptor.However, this bond is shown just as a single line with a positive(+) sign on the donor and negative sign(-) on the acceptor atom.

The co ordinate bond forms the basis of a whole class of compounds called co ordination compounds. In these compounds the transition metals, which have vacant d- orbitals act as electron acceptors(Lewis acids) and the electron donors are called ligands (Lewis bases).We will study co ordination chemistry in detail in some later posts. Here is an  example of such metal complex –


The central cobalt ion is accepting electrons from 4 ammonia and two chlorine ligands. All those bonds are co ordinate bonds and thus this is a co ordination compound.

The electron rich species are negatively charged ions or neutral molecules with lone pair/s.

These have melting and boiling points higher than the covalent compounds but lower than the ionic compounds. This means that, co ordinate covalent bonded compounds are more stable than the covalent compounds. However, the ionic bond is the strongest.

In the next post we shall start discussing secondary bonding in molecules.Till then ,

Be a perpetual student of life and keep learning ….

Good day !

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